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2-[1-[[[(2E)-3-chloro-2-propen-1-yl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one

UUID c977e2cd-c87b-4db4-888f-658e65a200c3
Flow Object IDfo-b06eb7f38ca1ac25
Source EF 3.1
Context Environmental → Air → High stack, >150 meters
CAS Numbers 99129-21-2
EC Numbers 619-396-7
prefLabel
Language Value Provenance
en 2-[1-[[[(2E)-3-chloro-2-propen-1-yl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one
altLabel ⓘ
Language Value Provenance
en 2-(N-{[(2E)-3-chloroprop-2-en-1-yl]oxy}propanimidoyl)-5-[2-(ethylsulfanyl)propyl]-3-hydroxycyclohex-2-en-1-one
en 2-Cyclohexen-1-one, 2-[1-[[[(2<em>E</em>)-3-chloro-2-propen-1-yl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-
en 2-Cyclohexen-1-one, 2-[1-[[[(2<em>E</em>)-3-chloro-2-propenyl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-
en 2-[1-[[[(2<em>E</em>)-3-Chloro-2-propen-1-yl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one
en <em>E</em>-Clethodim
en Arrow
en Centurion
en Centurion Plus
en Chevron RE 45601
en Clethodim MUP
en Clethodim T.G.
en Clethodime
en Legion Kombi
en Ogive
en Prism
en Prism (pesticide)
en RE 45601
en Section Three
en Select
en Select MAX
en Select Super 120EC
en Trigger
en Volunteer
en Clethodim
Definitions
Language Value Provenance
en An oxime O-ether resulting from the formal conversion ot the acyclic keto group of 5-[2-(ethylsulfanyl)propyl]-3-hydroxy-2-propionylcyclohex-2-en-1-one to the corresponding oxime with subsequent O-alkylation of the oxime by an (E)-3-chloroallyl group. It is used as a selective postemergence herbicide for the control of annual and perennial grasses in numerous crops, including alfalfa, celery, clover, conifers, cotton, cranberries, garlic, onions, ornamentals, peanuts, soybeans, strawberries, sugarbeet, sunflowers, and vegetables; the (−)-enantiomer has been reported to be more active than the (+)-enantiomer.
References
Shared Properties
Predicate Value
Formal charge 0
InChIKey SILSDTWXNBZOGF-JWGBMQLESA-N, SILSDTWXNBZOGF-KUZBFYBWSA-N
InChI InChI=1S/C17H26ClNO3S/c1-4-14(19-22-8-6-7-18)17-15(20)10-13(11-16(17)21)9-12(3)23-5-2/h6-7,12-13,20H,4-5,8-11H2,1-3H3/b7-6+,19-14+, InChI=1S/C17H26ClNO3S/c1-4-14(19-22-8-6-7-18)17-15(20)10-13(11-16(17)21)9-12(3)23-5-2/h6-7,12-13,20H,4-5,8-11H2,1-3H3/b7-6+,19-14?
IUPAC name 2-[(1E)-1-[(E)-3-chloroprop-2-enoxy]iminopropyl]-5-[2-(ethylthio)propyl]-3-hydroxy-1-cyclohex-2-enone, 2-[(E)-N-[(E)-3-chloranylprop-2-enoxy]-C-ethyl-carbonimidoyl]-5-(2-ethylsulfanylpropyl)-3-oxidanyl-cyclohex-2-en-1-one, 2-[(E)-N-[(E)-3-chloroallyloxy]-C-ethyl-carbonimidoyl]-5-(2-ethylsulfanylpropyl)-3-hydroxy-cyclohex-2-en-1-one, 2-[(E)-N-[(E)-3-chloroallyloxy]-C-ethyl-carbonimidoyl]-5-[2-(ethylthio)propyl]-3-hydroxy-cyclohex-2-en-1-one, 2-[(E)-N-[(E)-3-chloroprop-2-enoxy]-C-ethylcarbonimidoyl]-5-(2-ethylsulfanylpropyl)-3-hydroxycyclohex-2-en-1-one
Molecular formula C17H26ClNO3S
Molecular mass 359.919
Monoisotopic mass 359.13219
SMILES CC/C(=N\OC/C=C/Cl)/C1=C(CC(CC1=O)CC(C)SCC)O, CCC(=NOCC=CCl)C1=C(CC(CC1=O)CC(C)SCC)O, CCSC(C)CC1CC(=O)C(C(CC)=NOC/C=C/Cl)=C(O)C1

Source List References

List Version Source Flow UUID Source Flow Name
EF 3.1 c977e2cd-c87b-4db4-888f-658e65a200c3 clethodim

Concept Associations

Source List Source Flow Source Context Unit Match Type Conversion Provenance
EF 3.1 clethodim Emissions/Emissions to air/Emissions to non-urban air or from high stacks kg exactMatch —

Consolidated Field Provenance

0 total PROV activity record(s) for this flow.

Field Change Count Latest Time Transformers Latest Comment
altLabel 1 — consensus_match group_key=clethodim||dimension=Environmental > media=Air > indoor=Unknown; cas=99129-21-2; added Common Chemistry CAS names as altLabel: 2-Cyclohexen-1-one, 2-[1-[[[(2<em>E</em>)-3-chloro-2-propen-1-yl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-, 2-Cyclohexen-1-one, 2-[1-[[[(2<em>E</em>)-3-chloro-2-propenyl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-, 2-[1-[[[(2<em>E</em>)-3-Chloro-2-propen-1-yl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one, <em>E</em>-Clethodim, Arrow, Centurion, Centurion Plus, Chevron RE 45601, Clethodim MUP, Clethodim T.G., Clethodime, Legion Kombi, Ogive, Prism, Prism (pesticide), RE 45601, Section Three, Select, Select MAX, Select Super 120EC, Trigger, Volunteer; object_uuid=fo-b06eb7f38ca1ac25
cas_match_labels 1 — consensus_match group_key=clethodim||dimension=Environmental > media=Air > indoor=Unknown; group_sources=['chebi', 'pubchem']; cas_sources={'99129-21-2': ['chebi', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-b06eb7f38ca1ac25: {'99129-21-2': 'exactMatch'}

Context Attributes

AttributeValue
dimensionEnvironmental
mediaAir
strataHigh stack, >150 meters

Consensus Changes

Field Old Value New Value Comment
altLabel [{'@value': '2-(N-{[(2E)-3-chloroprop-2-en-1-yl]oxy}propanimidoyl)-5-[2-(ethylsulfanyl)propyl]-3-hydroxycyclohex-2-en-1-one', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'chebi_altlabels', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['label:2-(N-{[(2E)-3-chloroprop-2-en-1-yl]oxy}propanimidoyl)-5-[2-(ethylsulfanyl)propyl]-3-hydroxycyclohex-2-en-1-one', 'http://purl.obolibrary.org/obo/CHEBI_70721', 'EF 3.1'], 'prov:wasDerivedFrom': 'chebi synonym match'}}, {'@value': '2-[1-[[[(2E)-3-chloro-2-propen-1-yl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'chebi_altlabels', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['label:2-[1-[[[(2E)-3-chloro-2-propen-1-yl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one', 'http://purl.obolibrary.org/obo/CHEBI_70721', 'EF 3.1'], 'prov:wasDerivedFrom': 'chebi synonym match'}}] [{'@value': '2-(N-{[(2E)-3-chloroprop-2-en-1-yl]oxy}propanimidoyl)-5-[2-(ethylsulfanyl)propyl]-3-hydroxycyclohex-2-en-1-one', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'chebi_altlabels', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['label:2-(N-{[(2E)-3-chloroprop-2-en-1-yl]oxy}propanimidoyl)-5-[2-(ethylsulfanyl)propyl]-3-hydroxycyclohex-2-en-1-one', 'http://purl.obolibrary.org/obo/CHEBI_70721', 'EF 3.1'], 'prov:wasDerivedFrom': 'chebi synonym match'}}, {'@value': '2-[1-[[[(2E)-3-chloro-2-propen-1-yl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'chebi_altlabels', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['label:2-[1-[[[(2E)-3-chloro-2-propen-1-yl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one', 'http://purl.obolibrary.org/obo/CHEBI_70721', 'EF 3.1'], 'prov:wasDerivedFrom': 'chebi synonym match'}}, {'@value': '2-Cyclohexen-1-one, 2-[1-[[[(2<em>E</em>)-3-chloro-2-propen-1-yl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': '2-Cyclohexen-1-one, 2-[1-[[[(2<em>E</em>)-3-chloro-2-propenyl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': '2-[1-[[[(2<em>E</em>)-3-Chloro-2-propen-1-yl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': '<em>E</em>-Clethodim', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Arrow', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Centurion', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Centurion Plus', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Chevron RE 45601', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Clethodim MUP', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Clethodim T.G.', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Clethodime', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Legion Kombi', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Ogive', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Prism', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Prism (pesticide)', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'RE 45601', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Section Three', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Select', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Select MAX', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Select Super 120EC', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Trigger', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}, {'@value': 'Volunteer', '@language': 'en', 'source': {'prov:wasGeneratedBy': 'consensus_match', 'prov:wasAttributedTo': 'consensus-flow-list', 'prov:hadPrimarySource': ['CAS:99129-21-2', 'https://commonchemistry.cas.org/detail?cas_rn=99129-21-2'], 'prov:wasDerivedFrom': 'common chemistry CAS lookup'}}] group_key=clethodim||dimension=Environmental > media=Air > indoor=Unknown; cas=99129-21-2; added Common Chemistry CAS names as altLabel: 2-Cyclohexen-1-one, 2-[1-[[[(2<em>E</em>)-3-chloro-2-propen-1-yl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-, 2-Cyclohexen-1-one, 2-[1-[[[(2<em>E</em>)-3-chloro-2-propenyl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-, 2-[1-[[[(2<em>E</em>)-3-Chloro-2-propen-1-yl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one, <em>E</em>-Clethodim, Arrow, Centurion, Centurion Plus, Chevron RE 45601, Clethodim MUP, Clethodim T.G., Clethodime, Legion Kombi, Ogive, Prism, Prism (pesticide), RE 45601, Section Three, Select, Select MAX, Select Super 120EC, Trigger, Volunteer; object_uuid=fo-b06eb7f38ca1ac25
cas_match_labels None {'99129-21-2': 'exactMatch'} group_key=clethodim||dimension=Environmental > media=Air > indoor=Unknown; group_sources=['chebi', 'pubchem']; cas_sources={'99129-21-2': ['chebi', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-b06eb7f38ca1ac25: {'99129-21-2': 'exactMatch'}

PROV-O Consensus Activity Trail

No PROV-O consensus activities found for this flow.

Full Flow JSON

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